http://www.microsoft.com/whdc/system/platform/server/PAE/PAEmem.mspx

Memory Support and Windows Operating Systems

Operating systems based on Microsoft Windows NT technologies have always provided applications with a flat 32-bit virtual address space that describes 4 gigabytes (GB) of virtual memory. The address space is usually split so that 2 GB of address space is directly accessible to the application and the other 2 GB is only accessible to the Windows executive software.

The 32-bit versions of the Windows 2000 Advanced Server and Windows NT Server 4.0, Enterprise Edition, operating systems were the first versions of Windows to provide applications with a 3-GB flat virtual address space, with the kernel and executive components using only 1 GB. In response to customer requests, Microsoft has expanded the availability of this support to the 32-bit version of Windows XP Professional and all 32-bit versions of Windows Server 2003.

Windows 2000 Memory Support. With Windows 2000 Professional and Server, the maximum amount of memory that can be supported is 4 GB (identical to Windows NT 4.0, as described later in this section). However, Windows 2000 Advanced Server supports 8 GB of physical RAM and Windows 2000 Datacenter Server supports 32 GB of physical RAM using the PAE feature of the IA-32 processor family, beginning with Intel Pentium Pro and later.

Windows XP Professional and Windows Server 2003 Memory Support. The maximum amount of memory that can be supported on Windows XP Professional and Windows Server 2003 is also 4 GB. However, Windows Server 2003, Enterprise Edition supports 32 GB of physical RAM and Windows Server 2003, Datacenter Edition supports 64 GB of physical RAM using the PAE feature.